Team GB's Andy Murray will begin his Olympic challenge against Stanislas Wawrinka on Centre Court tomorrow.
The match will take place following the conclusion of Julia Goerges's match with Agnieszka Radwanska, which is scheduled to begin at noon.
Elsewhere, second seed Novak Djokovic takes on Fabio Fognini on Court One and Heather Watson meets Silvia Soler-Espinosa on Court 18.
In full (all first round):
Centre Court - noon start
Goerges vs. Radwanska, Wawrinka vs. Murray, Peer vs. Sharapova, Tsonga vs. Bellucci
Court One - noon start
Fognini vs. Djokovic, Errani vs. V Williams, Goffin vs. Monaco, Azarenka vs. Begu
Court Two - 11.30am start
Ferrer vs. Pospisil, Roddick vs. Klizan, Cetkovska vs. Kerber, Nishikori / Soeda vs. Federer / Wawrinka
Court Seven - 11.30am start
Men's Singles - 1st Round Stepanek vs. Davydenko, Zheng vs. Petrova, Radwanska / Radwanska vs. Cibulkova / Hantuchova, Berdych / Stepanek vs. Bracciali / Seppi
Court 11 - 11.30am start
Halep, Shvedova, Tursunov vs. Lopez, Nestor / Pospisil vs. Tecau / Ungur
Court 12 - 11.30am start
Tatishvili, Vogt, Lisicki vs. Jabeur, Chakhnashvili / Tatishvili vs. Klepac / Srebotnik, Djokovic / Troicki vs. Brunstrom / Lindstedt
Court 14 - 11.30am start
Soeda vs. Baghdatis, Robson vs. Safarova, Ito vs. Raonic, Bury / Mirnyi vs. Bhupathi / Bopanna
Court 15 - 11.30am start
Voskoboeva vs. Babos, Cilic, vs. Melzer, Hlavackova / Hradecka vs. Babos / Szavay, Cilic / Dodig vs. Cabal / Giraldo
Court 16 - start: 11.30am
Lepchenko vs. Cepede Royg, Kirilenko vs, Duque-Marino, (not before 2pm) Gasquet vs. Haase, Goerges / Gronefeld vs. Baltacha / Keothavong, Haase / Rojer vs. Paes / Vardhan
Court 17 - 11.30 start
Devvarman vs. Nieminen, Erakovic vs. Wozniak, (not before 2pm) Kohlschreiber vs. Kavcic, Kas / Petzschner vs. Davydenko / Youzhny
Court 18 - 11.30am start
Tomic vs. Nishikori, Soler-Espinosa vs. Watson, Hewitt vs. Stakhovsky, Cirstea / Halep vs. Williams / Williams (USA)
Court 19 - 11.30am start
Li / Zhang vs. Dulko / Suarez, Martinez Sanchez vs. Hercog, Medina Garrigues / Parra Santonja vs. Pennetta / Schiavone, Tipsarevic / Zimonjic vs. Klizan / Lacko
